• Flame Retardant (FR) and Antimicrobial Properties of Bifunctional Polyguanidine Salt Additives for Polypropylene (PP) Membrane Materials
  • Bowen Lv, Dongqing Liu , Tian Xu, Yuxuan Cheng, Sun Zhou, Mengyuan Zhang, and Qinxing Xie

  • State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Laboratory of Materials for Energy Storage, School of Material Science and Engineering, Tiangong University, Tianjin 300387, China

  • Polypropylene(PP) 멤브레인 소재를 위한 이중 기능성 폴리구아니딘 염 첨가제의 난연 및 향균 특성 연구
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Liu, R.; Qing, X. C.; Feng, Z. B.; Zhang, X. M.; Zhang, Y.; Zhang, M. Y.; Zhu, B. Y.; Li, Y.; Xie, L. Research Status of Modification Methods for Antimicrobial Function of Grafting Polymer Materials. Polym. Bull. 2023, 36, 564-573.
  •  
  • 2. Lv, T. J.; Zhang, X. D.; Gao, J. Q.; Liu, H. S.; Wang, J. Development of Plastics with Anti-bacterial Function. Liaoning Chemical Industry. 1999, 35-36.
  •  
  • 3. Hou, X. J.; Xue, B. X.; Liu, S. H.; Zhu, Y. L.; Niu, M.; Yang, Y. Z.; Zhang, L. Antibacterial Properties and Biosafety of Silvered Silica Modified Silicone Rubber. Polym. Mater. Sci. Eng. 2023, 39, 111-116.
  •  
  • 4. Tian, X.; Hua, T.; Poon, T.; Yang, Y. Y.; Hu, H.; Fu, J. M.; Li, J. H.; Niu, B. Study on Effects of Blending Fiber Type and Ratio on Antibacterial Properties of Chitosan Blended Yarns and Fabrics. Fibers Polym. 2022, 23, 2565-2576.
  •  
  • 5. Zhang, Z.; Li, J.; Li, C. J.; Chu, L. Q.; Guo, M.; Wang, Y. Research Progress of Antibacterial Agents Used in Protective Fiber Materials and Their Antibacterial and Antiviral Mechanisms. Petrochemical Technology. 2023, 52, 1609-1618.
  •  
  • 6. Liang, Y. Q.; Xu, J. X.; Ahmed, N.; Shi, J.; Wen, M. Y.; Yan, N. Construction of Biomass-based Flame-retardant, Antimicrobial and Hydrophobic Wood Coatings with POSS Organic-inorganic Nanoparticles. Eur. Polym. J. 2024, 219, 113370.
  •  
  • 7. Fonseca, J.; Cano-Sarabia, M.; Cortés, P.; Saldo, J.; Montpeyó, D.; Lorenzo, J.; Llagostera, M.; Imaz, I.; Maspoch, D. Metal-Organic Framework-Based Antimicrobial Touch Surfaces to Prevent Cross-Contamination. Adv. Mater. 2024, e2403813.
  •  
  • 8. Hemraz, U. D.; Lam, E.; Sunasee, R. Recent Advances in Cellulose Nanocrystals-based Antimicrobial Agents. Carbohydr. Polym. 2023, 315, 120987.
  •  
  • 9. Gong, Y. T.; Xu, X.; Aquib, M.; Zhang, Y. H.; Yang, W. T.; Chang, Y. X.; Peng, H.; Boyer, C.; Whittaker, A. K.; Fu, C. K. Ammonium, Phosphonium, and Sulfonium Polymers for Antimicrobial Applications: A Comparative Study. ACS Appl. Polym. Mater. 2024, 6, 6966-6975.
  •  
  • 10. Chen, Q.; Xu, Y. J.; Feng, J. Y.; Lv, X. S.; Fu, X. H.; Yuan, S. S. Hyperbranched Poly-L-Lysine Based Water-Insoluble Complexes as Antibacterial Agents with Efficient Antibacterial Activity And Cytocompatibility. Macromol. Biosci. 2023, 24, e2300388.
  •  
  • 11. Qiu, W. Z.; Zhao, Z. S.; Du, Y.; Hu, M. X.; Xu, Z. K. Antimicrobial Membrane Surfaces via Efficient Polyethyleneimine Immobilization and Cationization. Appl. Surf. Sci. 2017, 426, 972-979.
  •  
  • 12. Wang, Y. D.; Ma, L.; Wang, H.; Cheng, C. Z.; Yin, X. Z.; Zhu, Z. M. Fabrication of a Flame Retardant, Strong Mechanical Toughness and Antimicrobial Polylactic Acid by Chitosan Schiff Base/ammonium Polyphosphate. Polym. Degrad. Stab. 2023, 216, 110492.
  •  
  • 13. Wang, Q. F.; Zhao, G. L. Investigation of Flame Retardant Modification and Thermal Degradation of Insulating Paper. Appl. Chem. Industry. 2006, 517-519.
  •  
  • 14. Wan, C. Y.; Zhang, G. G.; Zhang, F. X. A Novel Guanidine Ammonium Phosphate for Preparation of a Reactive Durable Flame Retardant for Cotton Fabric. Cellulose. 2020, 27, 3469-3483.
  •  
  • 15. Fang, Y. C; Chen, L. X; Liu, J. J; Wu, L. S. Multi-functionalization of Cotton Fabrics with Excellent Flame Retardant, Antibacterial and Superhydrophobic Properties. Int. J. Biol. Macromol. 2023, 254, 127889.
  •  
  • 16. Seo, K. H; Lim, J. C. Phase Morphology and Foaming of Polypropylene/ethylene-octene Copolymer Blends. Polym. Korea. 2001, 25, 707-718.
  •  
  • 17. Běhálek, L.; Dobránsky, J.; Pollák, M.; Borůvka, M.; Brdlík, P. Application of Physical Methods for the Detection of a Thermally Degraded Recycled Material in Plastic Parts Made of Polypropylene Copolymer. Materials. 2021, 14, 552.
  •  
  • 18. Yang, X. L.; Liang, S. H.; Hou, Z. K.; Feng, D. L.; Xiao, Y.; Zhou, S. Z. Experimental Study on Strength of Polypropylene Fiber Reinforced Cemented Silt Soil. Appl. Sci.-Basel. 2022, 12, 8318.
  •  
  • 19. Fu, Q. W. Characterization of the Crystal Structure of Polypropylene. Biochem. 2020, 3, 99-101.
  •  
  • 20. Seifalian, A.; Basma, Z.; Digesu, A.; Khullar, V. Polypropylene Pelvic Mesh: What Went Wrong and What Will Be of the Future? Biomedicines. 2023, 11, 741.
  •  
  • 21. Ömer Fırat TURŞUCULAR. A Review on Boron and Its Derivatives Used in Flame Retardant (FR) Applications for Cotton Fiber or Various Cotton Textile Fabric Forms. Textile Sci. Fashion Tech. 2024, 10, 000742.
  •  
  • 22. Idumah, C. I. Emerging Advancements in Flame Retardancy of Polypropylene Nanocomposites. J. Thermoplast. Compos. Mater. 2022, 35, 2665-2704.
  •  
  • 23. Lee, J. H.; Nam, J. H.; Lee, D. H.; Kim, M. D.; Kong, J. H.; Lee, Y. K.; Nam, J. D. Flame Retardancy of Polypropylene/montmorillonite Nanocomposites with Halogenated Flame Retardants. Polym. Korea. 2003, 27, 569-575.
  •  
  • 24. Zheng, P. F.; Ping, G. S.; Li, F. T.; Zheng, H. G. Thermal Degradation and Flame Retardancy of Polypropylene/C60 Nanocomposites. Thermochim. Acta. 2008, 473, 106-108.
  •  
  • 25. Choi, H.; Kim, K.-J.; Lee, D. G. Antifungal Activity of the Cationic Antimicrobial Polymer-polyhexamethylene Guanidine Hydrochloride and Its Mode of Action. Fungal Biol. 2017, 121, 53-60.
  •  
  • 26. Sun, X. X.; Ji, J. H.; Zhang, W.; Wang, G. X.; Zhen, Z. C.; Wang, P. L. Guanidine-based Polymeric Microspheres with a Nonleaching, Antibacterial Performance. J. Appl. Polym. Sci. 2017, 134, 44821.
  •  
  • 27. Yu, T. H.; Ji, F. F.; Zhou, Y. J.; Ding, R. Y. Standardized Assessment Methodologies for Evaluating Antimicrobial Efficacy in Textile Materials. (in Chinese). Text. Test. Stand. 2023, 9, 9-12.
  •  
  • 28. Niro, A.; Pignatelli, F.; Fallico, M.; Sborgia, A.; Passidomo, F.; Gigliola, S.; Nacucchi, A.; Sborgia, G.; Boscia, G.; Alessio, G.; Boscia, F.; Addabbo, G.; Reibaldi, M.; Avitabile, T, Polyhexamethylene Biguanide Hydrochloride (PHMB)-properties and Application of an Antiseptic Agent. Eur. J. Ophthalmol. 2022, 33, 1724-6016.
  •  
  • 29. Huang, Z. C.; Yang, Y. D.; Chen, L. J.; Tang, G. Preparation of BN@APP/Waterborne Polyurethane Composites and Their Flame Retardant Properties. China Plastics Industry. 2022, 1, 124-129.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2024 Impact Factor : 0.6
  • Indexed in SCIE

This Article

  • 2025; 49(4): 411-416

    Published online Jul 25, 2025

  • 10.7317/pk.2025.49.4.411
  • Received on Oct 31, 2024
  • Revised on Jan 26, 2025
  • Accepted on Feb 15, 2025

Correspondence to

  • Bowen Lv, Dongqing Liu
  • State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Laboratory of Materials for Energy Storage, School of Material Science and Engineering, Tiangong University, Tianjin 300387, China

  • E-mail: ldqnov@163.com