• Preparation of a Biaxially Oriented Polypropylene (BOPP)/CaCO3 Film with High Haze and Its Performance Study
  • Zhengyu Yao*, Tianjiao Hou*,† , and Xuan Shen*, **,†

  • *State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, P.R. China
    **Zhangjiagang Institute of Nanjing Tech University, Suzhou 215600, P.R. China

  • 고헤이즈(High Haze) 특성을 가진 이축연신 폴리프로필렌/탄산칼슘 필름의 제조 및 성능 연구
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Masuda, J.; Ohkura, M. Preparation and Characterization of Biaxially Oriented Polypropylene Film with High Molecular Orientation in the Machine Direction by Sequential Biaxial Stretching. J. Appl. Polym. Sci. 2007, 106, 4031-4037.
  •  
  • 2. Siracusa, V.; Ingrao, C. Correlation Amongst Gas Barrier Behaviour, Temperature and Thickness in BOPP Films for Food Packaging Usage: A Lab-scale Testing Experience. Polym. Test. 2017, 59, 277-289.
  •  
  • 3. Nie, H. Y.; Walzak, M. J.; McIntyre, N. S. Scratch Resistance Anisotropy in Biaxially Oriented Polypropylene and Poly(ethylene terephthalate) Films. Appl. Surf. Sci. 2006, 253, 2320-2326.
  •  
  • 4. Song, Y. X.; Tzeng, P.; Grunlan, J. C. Super Oxygen and Improved Water Vapor Barrier of Polypropylene Film With Polyelectrolyte Multilayer Nanocoatings. Macromol. Rapid Comm. 2016, 37, 963-968.
  •  
  • 5. Zhang, H. Q.; Feng, X. H.; Wu, Y.; Wu, Z. H. Factors Influencing the Properties of UV-cured Self-matting Film. Prog. Org. Coat. 2024, 189, 108241.
  •  
  • 6. Nuntapichedkul, B.; Tantayanon, S.; Laohhasurayotin, K. Practical Approach in Surface Modification of Biaxially Oriented Polypropylene Films for Gravure Printability. Appl. Surf. Sci. 2014, 314, 331-340.
  •  
  • 7. Huang, M. M.; Dong, X.; Fu, D. S.; Huang, W. H.; Wu, L. M.; Huang, Q.; Wang, D. J. Effects of Ethylene Segments on the Crystallization and Tensile Properties of Biaxially Oriented Polypropylene. Acta Polym. Sin. 2014, 455-465.
  •  
  • 8. Vessot, K.; Messier, P.; Hyde, J. M.; Brown, C. A. Correlation Between Gloss Reflectance and Surface Texture in Photographic Paper. Scanning 2015, 37, 204-217.
  •  
  • 9. Lin, Y. J.; Dias, P.; Chum, S.; Hiltner, A.; Baer, E. Surface Roughness and Light Transmission of Biaxially Oriented Polypropylene Films. Polym. Eng. Sci. 2007, 47, 1658-1665.
  •  
  • 10. Yong, Q. W.; Xu, D.; Liu, Q.; Xiao, Y.; Wei, D. D. Advances in Polymer-based Matte Coatings: A Review. Polym. Adv. Technol. 2022, 33, 5-19.
  •  
  • 11. Klozinski, A.; Szczepanska, M.; Jakubowska, P.; Samujlo, B.; Barczewski, M.; Lota, G. The Influence of Calcium Carbonate and Its Modifications on the Extrusion Process and Selected Properties of Polypropylene Cast Films. Polimery 2022, 67, 509-521.
  •  
  • 12. Butt, M. A. Thin-film Coating Methods: A Successful Marriage of High-quality and Cost-effectiveness-a Brief Exploration. Coatings 2022, 12, 1115.
  •  
  • 13. Yong, Q. W.; Nian, F. W.; Liao, B.; Guo, Y.; Huang, L. P.; Wang, L.; Pang, H. Synthesis and Surface Analysis of Self-matt Coating Based on Waterborne Polyurethane Resin and Study on the Matt Mechanism. Polym. Bull. 2017, 74, 1061-1076.
  •  
  • 14. Yong, Q. W.; Nian, F. W.; Liao, B.; Huang, L. P.; Wang, L.; Pang, H. Synthesis and Characterization of Solvent-free Waterborne Polyurethane Dispersion with Both Sulfonic and Carboxylic Hydrophilic Chain-extending Agents for Matt Coating Applications. RSC Adv. 2015, 5, 107413-107420.
  •  
  • 15. Wang, X. T.; Song, K. Y. Improvement of Surface Coating and Interfacial Properties of Hot-waxed Wood Using Maleic Anhydride Grafted Polypropylene Wax. Forests 2022, 13, 1205.
  •  
  • 16. Ou, J. H.; Zhang, M.; Liu, H. L.; Zhang, L.; Pang, H. Matting Films Prepared from Waterborne Acrylic/micro-SiO2 Blends. J. Appl. Polym. Sci. 2015, 132, 41704.
  •  
  • 17. Yu, F. C.; Wang, B. L.; Cui, J. P.; Nan, D. M.; Li, Y. M.; Liu, Z. Y.; Tang, X. X.; He, L.; Zhang, J. B.; Liu, Y. S. Structure and Photocatalytic Properties of the Composite of Al-doped Porous ZnO Hollow Micro-spheres and Ag Nanoparticles. J. Nanophotonics 2021, 15, 046002.
  •  
  • 18. Yong, Q. W.; Liang, C. Z. Synthesis of An Aqueous Self-matting Acrylic Resin with Low Gloss and High Transparency via Controlling Surface Morphology. Polymers 2019, 11, 322.
  •  
  • 19. Yang, Z. Y.; Wu, J. B.; Ma, G. Z.; Hou, C. Y.; Niu, Y. X.; Duan, H. F.; Hao, X. G. Effect of the Particle Sizes of Silica on the Properties of UV-curing Matting Coatings. J. Coat. Technol. Res. 2021, 18, 183-192.
  •  
  • 20. Xu, Q. N.; Ji, T. C.; Tian, Q. F.; Su, Y. H.; Niu, L. Y.; Li, X. H.; Zhang, Z. J. Structural Adjustment of In Situ Surface-modified Silica Matting Agent and Its Effect on Coating Performance. Nano 2018, 13, 1850137.
  •  
  • 21. Çamurlu, H. E.; Kesmez, Ö.; Burunkaya, E.; Kiraz, N.; Yesil, Z.; Asiltürk, M.; Arpaç, E. Sol-gel Thin Films with Anti-reflective and Self-cleaning Properties. Chem. Pap. 2012, 66, 461-471.
  •  
  • 22. Järnström, J.; Sinervo, L.; Toivakka, M.; Peltonen, J. Topography and Gloss of Precipitated Calcium Carbonate Coating Layers on a Model Substrate. Tappi J. 2007, 6, 23-31.
  •  
  • 23. Shen, J.; Song, Z. Q.; Qian, X. R.; Liu, W. X. A Preliminary Investigation Into the Use of Acid-tolerant Precipitated Calcium Carbonate Fillers in Papermaking of Deinked Pulp Derived From Recycled Newspaper. Bioresources 2009, 4, 1178-1189.
  •  
  • 24. Gumfekar, S. P.; Kunte, K. J.; Ramjee, L.; Kate, K. H.; Sonawane, S. H. Synthesis of CaCO3-P(MMA-BA) Nanocomposite and Its Application in Water Based Alkyd Emulsion Coating. Prog. Org. Coat. 2011, 72, 632-637.
  •  
  • 25. Li, C. Q.; Liang, C.; Chen, Z. M.; Di, Y. H.; Zheng, S. L.; Wei, S.; Sun, Z. M. Surface Modification of Calcium Carbonate: A Review of Theories, Methods and Applications. J. Cent. South Univ. 2021, 28, 2589-2611.
  •  
  • 26. Thenepalli, T.; Jun, A. Y.; Han, C.; Ramakrishna, C.; Ahn, J. W. A Strategy of Precipitated Calcium Carbonate (CaCO3) Fillers for Enhancing the Mechanical Properties of Polypropylene Polymers. Korean J. Chem. Eng. 2015, 32, 1009-1022.
  •  
  • 27. Al-Samhan, M.; Al-Attar, F. Comparative Analysis of the Mechanical, Thermal and Barrier Properties of Polypropylene Incorporated with CaCO3 and Nano CaCO3. Surf. Interfaces 2022, 31, 102055.
  •  
  • 28. Oladele, I. O.; Akinwekomi, A. D.; Ibrahim, I. O.; Adegun, M. H.; Talabi, S. I. Assessment of Impact Energy, Wear Behavior, Thermal Resistance and Water Absorption Properties of Hybrid Bagasse Fiber/CaCO3 Reinforced Polypropylene Composites. Int. Polym. Process. 2021, 36, 205-212.
  •  
  • 29. Rahman, G. M. S.; Aftab, H.; Islam, M. S.; Bin Mukhlish, M. Z.; Ali, F. Enhanced Physico-mechanical Properties of Polyester Resin Film Using CaCO3 Filler. Fibers Polym. 2016, 17, 59-65.
  •  
  • 30. Hasan, M.; Chong, E. W. N.; Jafarzadeh, S.; Paridah, M. T.; Gopakumar, D. A.; Tajarudin, H. A.; Thomas, S.; Khalil, H. Enhancement in the Physico-mechanical Functions of Seaweed Biopolymer Film via Embedding Fillers for Plasticulture Application-a Comparison with Conventional Biodegradable Mulch Film. Polymers 2019, 11, 210.
  •  
  • 31. Chen, P. C.; Wan, L. S.; Xu, Z. K. Bio-inspired CaCO3 Coating for Superhydrophilic Hybrid Membranes With High Water Permeability. J. Mater. Chem. 2012, 22, 22727-22733.
  •  
  • 32. Pechyen, C.; Ummartyotin, S. Development of Isotactic Polypropylene and Stearic Acid-modified Calcium Carbonate Composite: A Promising Material for Microwavable Packaging. Polym. Bull. 2017, 74, 431-444.
  •  
  • 33. Liu, B. Y.; Zeng, J. S.; Li, P. F.; Kui, M. H.; Li, J. P.; Chen, K. F. Development of Flexible Nanocellulose-based Composites with Enhanced Hydrophobicity and Improved Haze for Efficient Light Management in Solar Cells. Chem. Eng. J. 2024, 498, 155273.
  •  
  • 34. Avella, M.; Cosco, S.; Di Lorenzo, M. L.; Di Pace, E.; Errico, M. E.; Gentile, G. Nucleation Activity of Nanosized CaCO3 on Crystallization of Isotactic Polypropylene, in Dependence on Crystal Modification, Particle Shape, and Coating. Eur. Polym. J. 2006, 42, 1548-1557.
  •  
  • 35. Qiu, J.; Lyu, J. W.; Yang, J. L.; Cui, K. B.; Liu, H. Z.; Wang, G. F.; Liu, X. Review on Preparation, Modification and Application of Nano-Calcium Carbonate. Part. Part. Syst. Char. 2024, 41, 2400097.
  •  
  • 36. Kamal, M.; Sharma, C. S.; Upadhyaya, P.; Verma, V.; Pandey, K. N.; Kumar, V.; Agrawal, D. D. Calcium Carbonate (CaCO3) Nanoparticle Filled Polypropylene: Effect of Particle Surface Treatment on Mechanical, Thermal, and Morphological Performance of Composites. Appl.Polym.Sci. 2012, 124, 2649-2656.
  •  
  • 37. Praditthama, A.; Charitngama, N.; Puttajana, S.; Atongb, D.; Pechyen, C. Surface Modified CaCO3 by Palmitic Acid as Nucleating Agents for Polypropylene Film: Mechanical, Thermal and Physical Properties. Energy Procedia 2014, 56, 264-273.
  •  
  • 38. Li, X. F.; Lu, X. L. Morphology of Polyvinylidene Fluoride and Its Blend in Thermally Induced Phase Separation Process. J. Appl. Polym. Sci. 2006, 101, 2944-2952.
  •  
  • 39. Shelesh-Nezhad, K.; Orang, H.; Motallebi, M. Crystallization, Shrinkage and Mechanical Characteristics of Polypropylene/CaCO3 Nanocomposites. J. Thermoplast. Compos. Mater. 2013, 26, 544-554.
  •  
  • 40. Zhu, Y. D.; Allen, G. C.; Jones, P. G.; Adams, J. M.; Gittins, D. I.; Heard, P. G.; Skuse, D. R. Dispersion Characterisation of CaCO3 Particles in PP/CaCO3 Composites. Compos Part A-Appl S. 2014, 60, 38-43.
  •  
  • 41. Castejón, P.; Antunes, M.; Arencón, D. Development of Inorganic Particle-Filled Polypropylene/High Density Polyethylene Membranes via Multilayer Co-Extrusion and Stretching. Polymers 2021,13, 306.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2024 Impact Factor : 0.6
  • Indexed in SCIE

This Article

  • 2026; 50(3): 402-409

    Published online May 25, 2026

  • 10.7317/pk..2026.50.3.402
  • Received on Mar 13, 2025
  • Revised on Nov 27, 2025
  • Accepted on Jan 15, 2026

Correspondence to

  • Tianjiao Hou* , Xuan Shen*, **
  • *State Key Laboratory of Materials-oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, P.R. China
    **Zhangjiagang Institute of Nanjing Tech University, Suzhou 215600, P.R. China

  • E-mail: hou_tianjiao@njtech.edu.cn, shenxuan@njtech.edu.cn