• Aligned Non-Oxidized Graphene Flake/PDMS Composites with Enhanced Mechanical Properties
  • Ja Yoon Lee, In-Hyeok Hwang, Saeed Habibpour*, and Yun-Seok Jun

  • Department of Polymer Engineering, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48513, Korea
    *Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario, Canada N2L 3G1

  • 기계적 물성이 향상된 배향 비산화 그래핀/PDMS 복합재
  • 이자윤 · 황인혁 · Saeed Habibpour* · 전윤석

  • 국립 부경대학교 고분자공학전공, *워털루 대학교 화학공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.


References
  • 1. Kiran, M. D.; Govindaraju, H. K.; Jayaraju, T.; Kumar, N. Review-Effect of Fillers on Mechanical Properties of Polymer Matrix Composites. Mater. Today. Proc. 2018, 5, 22421-22424.
  •  
  • 2. Pinto, G. M.; Cremonezzi, J. M. O.; Ribeiro, H.; Andrade, R. J. E.; Demarquette, N. R.; Fechine, G. J. M. From Two-Dimensional Materials to Polymer Nanocomposites with Emerging Multifunctional Applications: A Critical Review. Polym. Compos. 2023, 44, 1438-1470.
  •  
  • 3. Qadir, A.; Le, T. K.; Malik, M.; Amedome Min-Dianey, K. A.; Saeed, I.; Yu, Y.; Choi, J. R.; Pham, P. V. Representative 2D-Material-Based Nanocomposites and Their Emerging Applications: A Review. RSC Adv. 2021, 11, 23860-23880.
  •  
  • 4. Jun, Y. S.; Sy, S.; Ahn, W.; Zarrin, H.; Rasen, L.; Tjandra, R.; Amoli, B. M.; Zhao, B.; Chiu, G.; Yu, A. Highly Conductive Interconnected Graphene Foam Based Polymer Composite. Carbon 2015, 95, 653-658.
  •  
  • 5. Pang, Y.; Yang, J.; Curtis, T. E.; Luo, S.; Huang, D.; Feng, Z.; Morales-Ferreiro, J. O.; Sapkota, P.; Lei, F.; Zhang, J.; Zhang, Q.; Lee, E.; Huang, Y.; Guo, R.; Ptasinska, S.; Roeder, R. K.; Luo, T. Exfoliated Graphene Leads to Exceptional Mechanical Properties of Polymer Composite Films. ACS Nano 2019, 13, 1097-1106.
  •  
  • 6. Garg, A.; Basu, S.; Mahajan, R. L.; Mehta, R. Effect of RGO Synthesized from Different Precursors on the Enhancement in Mechanical Properties of GFRPs. Sci. Rep. 2025, 15, 1-18.
  •  
  • 7. Seo, J. H.; Yang, H. S.; Seo, M. H.; Kim, S. J.; Lee, J.; Kee, S.; Habibpour, S.; Lim, S. N.; Ahn, W.; Jun, Y. S. Aligning Graphene Sheets in Aerogel-Based Composites for Enhanced Electromagnetic Interference Absorption. Carbon 2025, 242, 120463-120474.
  •  
  • 8. Chatterjee, S.; Nafezarefi, F.; Tai, N. H.; Schlagenhauf, L.; Nüesch, F. A.; Chu, B. T. T. Size and Synergy Effects of Nanofiller Hybrids Including Graphene Nanoplatelets and Carbon Nanotubes in Mechanical Properties of Epoxy Composites. Carbon 2012, 50, 5380-5386.
  •  
  • 9. Madhad, H. V.; Mishra, N. S.; Patel, S. B.; Panchal, S. S.; Gandhi, R. A.; Vasava, D. V. Graphene/Graphene Nanoplatelets Reinforced Polyamide Nanocomposites: A Review. High Perform. Polym. 2021, 33, 981-997.
  •  
  • 10. Li, Y.; Wang, S.; Wang, Q.; Xing, M. A Comparison Study on Mechanical Properties of Polymer Composites Reinforced by Carbon Nanotubes and Graphene Sheet. Compos. Part B Eng. 2018, 133, 35-41.
  •  
  • 11. Yang, C. K.; Lee, Y. R.; Hsieh, T. H.; Chen, T. H.; Cheng, T. C. Mechanical Property of Multiwall Carbon Nanotube Reinforced Polymer Composites. Polym. Polym. Compos. 2018, 26, 99-104.
  •  
  • 12. Gholampour, A.; Valizadeh Kiamahalleh, M.; Tran, D. N. H.; Ozbakkaloglu, T.; Losic, D. From Graphene Oxide to Reduced Graphene Oxide: Impact on the Physiochemical and Mechanical Properties of Graphene-Cement Composites. ACS Appl. Mater. Interfaces 2017, 9, 43275-43286.
  •  
  • 13. Marsden, A. J.; Skilbeck, M.; Healey, M.; Thomas, H. R.; Walker, M.; Edwards, R. S.; Garcia, N. A.; Vuković, F.; Jabraoui, H.; Walsh, T. R.; Rourke, J. P.; Wilson, N. R. From Graphene to Graphene Oxide: The Importance of Extended Topological Defects. Phys. Chem. Chem. Phys. 2022, 24, 2318-2331.
  •  
  • 14. Kim, H. J.; Lee, S. M.; Oh, Y. S.; Yang, Y. H.; Lim, Y. S.; Yoon, D. H.; Lee, C.; Kim, J. Y.; Ruoff, R. S. Unoxidized Graphene/Alumina Nanocomposite: Fracture-and Wear-Resistance Effects of Graphene on Alumina Matrix. Sci. Rep. 2014, 4, 1-10.
  •  
  • 15. Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.; Sun, Z.; Slesarev, A.; Alemany, L. B.; Lu, W.; Tour, J. M. Improved Synthesis of Graphene Oxide. ACS Nano 2010, 4, 4806-4814.
  •  
  • 16. Kim, J.; Yoon, G.; Kim, J.; Yoon, H.; Baek, J.; Lee, J. H.; Kang, K.; Jeon, S. Extremely Large, Non-Oxidized Graphene Flakes Based on Spontaneous Solvent Insertion into Graphite Intercalation Compound. Carbon 2018, 139, 309-316.
  •  
  • 17. Monshi, A.; Foroughi, M. R.; Monshi, M. R. Modified Scherrer Equation to Estimate More Accurately Nano-Crystallite Size Using XRD. World J. Nano Sci. Eng. 2012, 02, 154-160.
  •  
  • 18. Holzwarth, U.; Gibson, N. The Scherrer Equation versus the “Debye-Scherrer Equation.” Nat. Nanotechnol. 2011, 6, 534.
  •  
  • 19. Shahriary, L.; Athawale, A. A. Graphene Oxide Synthesized by Using Modified Hummers Approach. Int. J. Renew. Energy Environ. Eng. 2014, 02, 58-63.
  •  
  • 20. Papageorgiou, D. G.; Kinloch, I. A.; Young, R. J. Mechanical Properties of Graphene and Graphene-Based Nanocomposites. Prog. Mater. Sci. 2017, 90, 75-127.
  •  
  • 21. Balandin, A. A.; Ghosh, S.; Bao, W.; Calizo, I.; Teweldebrhan, D.; Miao, F.; Lau, C. N. Superior Thermal Conductivity of Single-Layer Graphene. Nano Lett. 2008, 8, 902-907.
  •  
  • 22. Kim, J.; Han, N. M.; Kim, J.; Lee, J.; Kim, J. K.; Jeon, S. Highly Conductive and Fracture-Resistant Epoxy Composite Based on Non-Oxidized Graphene Flake Aerogel. ACS Appl. Mater. Interfaces. 2018, 10, 37507-37516.
  •  
  • 23. Shenoy, V. B. Chemically Derived Graphene Oxide. Nat. Chem. 2010, 2, 581-587.
  •  
  • 24. Sengupta, I.; Chakraborty, S.; Talukdar, M. Thermal Reduction of Graphene Oxide : How Temperature in Fl Uences Purity. J. Mater. Res. 2018, 33, 4113-4122.
  •  
  • 25. Borah, B.; Dash, R. K. Improved Dielectric Properties of RGO/PDMS Composites by Incorporation of Ag Nanoparticles. J. Mater. Sci. Mater. Electron 2022, 33, 12334-12350.
  •  
  • 26. Xu, P.; Panchapakesan, B. Mechancial Properties of Reduced Graphene Oxide Polymer Composites. NSTI-Nanotech. 2013, 1, 502-505.
  •  
  • 27. Labrague, G.; Gomez, F.; Chen, Z. Characterization of Buried Interfaces of Silicone Materials in Situ to Understand Their Fouling-Release, Antifouling, and Adhesion Properties. Langmuir 2024, 40, 9345-9361.
  •  
  • 28. Huang, Y.; Zhang, X.; Zhu, T.; Wang, Y.; Hu, N.; Ren, Z.; Yu, X.; Nguyen, D. H.; Zhang, C.; Liu, T. Aligned Porous and Anisotropic Nanocomposite Hydrogel with High Mechanical Strength and Superior Puncture Resistance by Reactive Freeze-Casting. Chem. Mater. 2023, 35, 5809-5821.
  •  
  • 29. Chu, K.; Wang, F.; Wang, X. hu; Huang, D. jian. Anisotropic Mechanical Properties of Graphene/Copper Composites with Aligned Graphene. Mater. Sci. Eng. A 2018, 713, 269-277.
  •  
  • 30. Niu, T.; Cao, G.; Xiong, C. Fracture Behavior of Graphene Mounted on Stretchable Substrate. Carbon 2016, 109, 852-859.
  •  
  • 31. Hu, Y.; Ding, J. L.; Chen, Y. Effects of Nanofiller Geometries and Interfacial Properties on the Mechanical Performance of Polymer Nanocomposites—A Numerical Study. Polym. Polym. Compos. 2021, 29, S19-S35.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2024 Impact Factor : 0.6
  • Indexed in SCIE

This Article

  • 2026; 50(1): 177-185

    Published online Jan 25, 2026

  • 10.7317/pk.2026.50.1.177
  • Received on Sep 29, 2025
  • Revised on Dec 2, 2025
  • Accepted on Dec 3, 2025

Correspondence to

  • Yun-Seok Jun
  • Department of Polymer Engineering, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48513, Korea

  • E-mail: ysjun@pknu.ac.kr